عنوان المقالة:دراسة الخواص الطيفية والحرارية والكهروكيميائية لمواد جديدة مستقر حراريا زرقاء خفيفة ومستمدة من مادة البولي أميد العطرية Study of Spectral, Thermal and Electrochemical Properties of New Thermally Stable Blue Light Emitting Materials Based Aromatic Polyamides
ازهر كامل رشيد | Azhar Kamil Rashid | 7776
- نوع النشر
- مجلة علمية
- المؤلفون بالعربي
- ازهر كامل رشيد
- المؤلفون بالإنجليزي
- Azhar Kamil Rashid
- الملخص العربي
- In this study, new triphenylamine with aromatic diacid monomers, 4,4'-dicarboxy-4''-acetyl-triphenylamine (AC1), 4,4'-dicarboxy-4''- ethyl-triphenylamine (AC2), 4,4'-dicarboxy-4''-methoxy-triphenylamine (AC3) were successfully synthesized by the aromatic nucleophilic displacement reaction of 4-fluorobenzonitrile with three aniline-derivatives using sodium hydride as the base, followed by alkaline hydrolysis of the di-cyanides intermediates (CY1, CY2, CY3). From these di-acids monomers, a series of poly(amine-amide)s were prepared by the phosphorylation poly-condensation reaction with different aromatic diamines. FTIR, 1H and 13C NMR spectroscopic techniques were used to identify the chemical structures of all resultant compounds and poly(amine-amide)s. These aromatic poly(amineamide) s have a good solubility in several organic solvents and gave strong and tough thin films via solution casting. They exhibited excellent thermal stability associated with high glass transition temperatures (Tg). In dilute N-methyl pyrrolidone solution, these polymers exhibited a strong photoluminescence in the blue region. Cyclic voltammetry of the results polyamides films cast onto an ITO-coated glass substrate in dry acetonitrile containing 0.1 M of tetrabutylammonium perchlorate as an electrolyte exhibited one oxidation redox couples.
- الملخص الانجليزي
- ---
- تاريخ النشر
- 30/04/2016
- الناشر
- Chemic Publishing Co
- رقم المجلد
- 28
- رقم العدد
- 8
- ISSN/ISBN
- 1739-1746
- رابط DOI
- http://dx.doi.org/10.14233/ajchem.2016.19807
- الصفحات
- 1739-1746
- رابط الملف
- تحميل (143 مرات التحميل)
- رابط خارجي
- http://www.asianjournalofchemistry.co.in/User/SearchArticle.aspx?Volume=&Issue=&Article=&Criteria=Study%20of%20Spectral,%20Thermal%20and%20Electrochemical%20Properties%20of%20New%20Thermally%20Stable%20Blue%20Light%20Emitting%20Materials%20Based%20Aromatic%20Polyamides
- الكلمات المفتاحية
- Hole-transporting materials, Triphenylamine, Emitting layer