عنوان المقالة:تحضير والتشخيص الطيفي ودراسة الفعالية الميكروبية لليكاند شف مع معقداتة المختلطة مع 1و10-فيناثرولين Mixed-1,10-phenanthroline with Mn(II), Cu(II),Co(II), Hg(II) and Ni(II) complexes Synthesis, Antimicrobial Activity and Spectroscopic Characterization of Binuclear Schiff Base
Rehab K. Al-Shemary , Eman Mutar Atiyah , Alaa Majid Sadiq
الملخص العربي
A new series of mixed complexes were synthesized as[[Mn2
(phen)2
(L)] +2
,[Co (phen)2
(L)(H2O)2
]
+2
, [Ni2
(phen)2
(L)]+2
,
[Cu2
(phen)2
(L)]+2and [Hg2
(phen)2
(L) (H2O)2
]
+2by the template reaction between H2L= [2E,2'E)-2,2'-(biphenyl-4,4'-diylbis(azan-1-yl-1-
ylidene))diacetic acid],phen = 1,10-phenanthroline; and M(II) =Mn(II), Co(II), Cu(II),Ni(II) and Hg(II)chloride salts.The structures of
the compounds elucidated by IR, elemental analysis, and 13C and 1H NMR (only ligand (H2L)).The complexes have 1:2electrolyte
behavior in ethanol solution. The mixed complexes, their free ligands alongside the corresponding metal salts were screened against
selected four bacterial isolates as (Staphylococcus aureus), (Escherichia coli), Bacillus and (Pseudomonas).All the mixed complexes
showed enhanced antibacterial activities compared to their free ligands
تاريخ النشر
02/07/2016
الناشر
Rehab K. Al-Shemary , Eman Mutar Atiyah , Alaa Majid Sadiq
إيمان مطر عطيه | Eman Mutar Atiyah | 11667