عنوان المقالة:One-step electrosynthesis of MnO2/rGO nanocomposite and its enhanced electrochemical performance One-step electrosynthesis of MnO2/rGO nanocomposite and its enhanced electrochemical performance
جمعه عبدالجواد محمد على | Gomaa A. M. Ali | 20627
نوع النشر
مجلة علمية
المؤلفون بالعربي
Gomaa A.M. Ali, Mashitah M. Yusoff, H.Algarni, Kwok Feng Chong
المؤلفون بالإنجليزي
Gomaa A.M. Ali, Mashitah M. Yusoff, H.Algarni, Kwok Feng Chong
الملخص العربي
We present a facile one-step electrochemical approach to generate MnO2/rGO nanocomposite from a mixture of Mn3O4 and graphene oxide (GO). The electrochemical conversion of Mn3O4 into MnO2 through potential cycling is expedited in the presence of GO while the GO is reduced into reduced graphene oxide (rGO). The MnO2 nanoparticles are evenly distributed on the rGO nanosheets and act as the spacer to prevent rGO nanosheets from restacking. This unique structure provides high electroactive surface area (1173 m2 g−1) that improves ions diffusion within the MnO2/rGO structure. As a result, the MnO2/rGO nanocomposite exhibits high specific capacitance of 473 F g−1 at 0.25 A g−1, which is remarkably higher (3 times) than the Mn3O4/GO prior conversion. In addition, the electrosynthesized nanocomposite shows higher conductivity and excellent potential cycling stability of 95% at 2000 cycles.
الملخص الانجليزي
We present a facile one-step electrochemical approach to generate MnO2/rGO nanocomposite from a mixture of Mn3O4 and graphene oxide (GO). The electrochemical conversion of Mn3O4 into MnO2 through potential cycling is expedited in the presence of GO while the GO is reduced into reduced graphene oxide (rGO). The MnO2 nanoparticles are evenly distributed on the rGO nanosheets and act as the spacer to prevent rGO nanosheets from restacking. This unique structure provides high electroactive surface area (1173 m2 g−1) that improves ions diffusion within the MnO2/rGO structure. As a result, the MnO2/rGO nanocomposite exhibits high specific capacitance of 473 F g−1 at 0.25 A g−1, which is remarkably higher (3 times) than the Mn3O4/GO prior conversion. In addition, the electrosynthesized nanocomposite shows higher conductivity and excellent potential cycling stability of 95% at 2000 cycles.
تاريخ النشر
01/09/2017
الناشر
Ceramics International
رقم المجلد
44
رقم العدد
7
الصفحات
7799-7807
رابط خارجي
https://www.sciencedirect.com/science/article/pii/S0272884218302232
الكلمات المفتاحية
Manganese oxideEnergy storageSupercapacitorsElectron transferGraphene
رجوع