عنوان المقالة:معقدات ثنائية النواة لقاعدة شف متعددة الاسنان تحضير , تشخيص و دراسة للمضادالجراثيم Binuclear metal complexes of polydentate Schiff-base: synthesis, characterisation and antibacterial studies
رياض محمود احمد | Riyadh Mahmood Ahmed | 12000
نوع النشر
مجلة علمية
المؤلفون بالعربي
حسن احمد حسن /نصري جاسم حسين / انعام اسماعيل يوسف/ رياض محمود احمد
المؤلفون بالإنجليزي
Hasan A. Hasan/ Nasry J. Hussien /Enaam I. Yousif/ Riyadh M. Ehmad
الملخص العربي
The new Co(II), Cu(II), Zn(II) and Cd(II) complexes with a multidentate Schiff-base ligand [Benzen1,4-dicarboxaldehyde bis-Semicarbazone] [H2L] are reported. The ligand H2L was derived from the condensation reaction of Benzen1,4-dicarboxaldehyde and Semicarbazidehydrochloride. The complexes were prepared from the reaction of the corresponding metal chloride with the ligand. The ligand and its metal complexes were characterised by spectroscopic methods (FTIR, UV-Vis,1H NMR, A.A), chloride content, conductance and melting point measurements. These studies revealed complexes of the general formulae [M2(L)2] with tetrahedral geometries for CoII, ZnII and CdII complexes while square planar geometries have been suggested for CuII complex. Biological activity of the ligand and its metal complexes against gram positive bacterial strain Bacillus (G+) and gram negative bacteria Pseudomonase (G-) revealed that the metal complexes become less resistive to the microbial activities as compared to the free ligand.
تاريخ النشر
09/05/2013
الناشر
Journal of the college of basic education
رقم المجلد
19
رقم العدد
78
رابط الملف
تحميل (257 مرات التحميل)
الكلمات المفتاحية
Schiff-base ligand;Benzen1,4-dicarboxaldehyde bis-Semicarbazone; Binuclear complexes; structural and antibacterial studies.
رجوع