عنوان المقالة:ليكاند الداي ثايوكاربميت الجديد لتكوين معقد:التحضير والتحليل الطيفي والنشاط البكتيري New Bis(dithiocarbamate) Ligand for Complex Formation; Synthesis, Spectral Analysis and Bacterial Activity
ا.د. انعام اسماعيل يوسف | Enaam Ismail Yousif | 22219
- نوع النشر
- مجلة علمية
- المؤلفون بالعربي
- انعام اسماعيل يوسف وحسن احمد حسن
- المؤلفون بالإنجليزي
- Enaam I. Yousif and Hasan A. Hasan
- الملخص العربي
- A range of macrocyclic dinuclear metal (II) dithiocarbamate-based complexes are reported. The preparation of complexes was accomplished from either mixing of the prepared ligand with a metal ion or through a template one-pot reaction. The preparation of the bisamine precursor was achieved through several synthetic steps. The free ligand; potassium 2,2'-(biphenyl-4,4'-diylbis(azanediyl))bis(1-chloro-2-oxoethane-2,1- diyl)bis(cyclohexylcarbamodithioate) (L) was yielded from the addition of CS2 to a bis-amine precursor in KOH medium.A variety of analytical and physical methods were implemented to characterise ligand and its complexes. The analyses were based on spectroscopic techniques (FTIR, UV-Vis, mass spectroscopy and 1H, 13C-NMR spectroscopy), melting points, elemental analysis, thermal properties, magnetic susceptibility and conductance. The analytical and physical techniques confirmed the formation of macrocyclic complexes of the general formulae [M(L)]2 (M= MnII, CoII, NiII, CuII, ZnII and CdII). The proposed structure around MnII, CoII, ZnII and CdII is a tetrahedral, while NiII and CuII complexes adopt square planar geometries. The prepared compounds were screened against four bacterial species (Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Bacillus stubtilis). The anti-bacterial test indicated that the complexes are more active against these bacterial strains, compared with the free ligand.
- الملخص الانجليزي
- A range of macrocyclic dinuclear metal (II) dithiocarbamate-based complexes are reported. The preparation of complexes was accomplished from either mixing of the prepared ligand with a metal ion or through a template one-pot reaction. The preparation of the bisamine precursor was achieved through several synthetic steps. The free ligand; potassium 2,2'-(biphenyl-4,4'-diylbis(azanediyl))bis(1-chloro-2-oxoethane-2,1- diyl)bis(cyclohexylcarbamodithioate) (L) was yielded from the addition of CS2 to a bis-amine precursor in KOH medium.A variety of analytical and physical methods were implemented to characterise ligand and its complexes. The analyses were based on spectroscopic techniques (FTIR, UV-Vis, mass spectroscopy and 1H, 13C-NMR spectroscopy), melting points, elemental analysis, thermal properties, magnetic susceptibility and conductance. The analytical and physical techniques confirmed the formation of macrocyclic complexes of the general formulae [M(L)]2 (M= MnII, CoII, NiII, CuII, ZnII and CdII). The proposed structure around MnII, CoII, ZnII and CdII is a tetrahedral, while NiII and CuII complexes adopt square planar geometries. The prepared compounds were screened against four bacterial species (Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Bacillus stubtilis). The anti-bacterial test indicated that the complexes are more active against these bacterial strains, compared with the free ligand.
- تاريخ النشر
- 01/03/2017
- الناشر
- IBN AL- HAITHAM J. FO R PURE & APPL. SC I
- رقم المجلد
- 30
- رقم العدد
- 1
- الصفحات
- 73-87
- رابط الملف
- تحميل (771 مرات التحميل)
- الكلمات المفتاحية
- Bis(dithiocarbamate) ligand; Metal complexes; Spectral studies; Thermal