عنوان المقالة:التركيب البلوري لـ ((E)-4-benzylidene-6-phenyl- 1,2,3,4,7,8,9,10-octahydrophenanthridine)) Crystal structure of (E)-4-benzylidene-6-phenyl- 1,2,3,4,7,8,9,10-octahydrophenanthridine
أ. د. محمد جابر الجبوري | Mohamad J. Al-Jeboori | 4933
- نوع النشر
- مجلة علمية
- المؤلفون بالعربي
- محمد جابر الجبوري, اليس بريك, كاري ميلر, هيرمن بوتكايدر, بيداء كريم الربيعي
- المؤلفون بالإنجليزي
- Baidaa K. Al-Rubaye, Alice Brink, Gary J. Miller, Herman Potgieter and Mohamad J. Al-Jeboor
- الملخص العربي
- The preparation of the title compound, C26H25N, was achieved by the condensation of an ethanolic mixture of benzaldehyde, cyclohexanone and ammonium acetate in a 2:1:1 molar ratio. There are two crystallographically independent molecules in the asymmetric unit. The two cyclohexyl rings adopt an anti-envelope conformation with the benzyl moiety adopting a cis conformation with respect to the nitrogen atom of the phenanthridine segment. In the crystal, molecules are linked through C—H N interactions into hydrogen-bonded chains that are further arranged into distinct layers by weak offset – interactions.
- تاريخ النشر
- 01/07/2017
- الناشر
- .Acta Cryst
- رقم المجلد
- رقم العدد
- 73
- ISSN/ISBN
- 2056-9890
- الصفحات
- 1092–1096
- الكلمات المفتاحية
- crystal structure; Mannich reaction; phenanthridine moiety; C—H N interactions; – interactions; Hirschfeld surfaces.