عنوان المقالة:تحضير وتشخيص بعض المعقدات الجديدة مع قاعدة شف جديدة نوع((N2O2 مشتقة من حامض الكلايوكسيلك مع إثيلين ثنائي أمين Synthesis, Characterization of New Tetradentate Schiff Base Ligand Type (N2O2) Derived from Glyoxylic Acid and Ethylenediamine and It's complexes with Mn(II), Co(II), Ni(II), Cu(II) and Hg(II) ions.
رحاب كاظم الشمري , جاسم شهاب سلطان و ساجد محمود لطيف
المؤلفون بالإنجليزي
R.K.Al-Shemary J.S.Sultan S.M.Lateef
الملخص العربي
The new tetradentate Sciff base ligand H2L(C6H8N2O4) type (N2O4) as donor atoms, namely [2,2׳ -(ethane-1,2- diylbis (azan-1-yl-ylidene )diacetic acid)] waspreparedfrom condensation of glyoxylic and with ethylenediamine in ethanol as a solvent in presence of drops of 48% HBr.Thestructure of
ligand (H2L) was characterized by, IR,U.V-Vis.,1H-,13C-NMR , Mass spectrophotometer, melting pointand elemental microanalysis C.H.N.
Metal complexes of the ligand(H2L) in general formula [M(L)(H2O)2],where M=Mn(II), Co(II), Ni(II), Cu(II) and Hg(II); L=(C6H8N2O4)weresynthesized and characterized by, Atomic absorption,FT- IR , U.V-Vis. spectra, molar conductivityandmagnetic susceptibility, (Co+2,Ni+2, Cu+2, Mn+2, Hg+2)complexes, it found that all complexes showed octahedral geometries.And in vitro tests for antibacterial and antifungal activity showed that most of the prepared compounds display a good activity toStaphylococcus aureus), (Escherichia coli) and (Candida albicans).
تاريخ النشر
15/10/2018
الناشر
مجلة ابن الهيثم
رقم المجلد
رقم العدد
الكلمات المفتاحية
Synthesis, Characterization, Schiff base, glyoxylic acid, Enylenediamineand metal ions
رحاب كاظم رحيم | rehab alshemary | 4486