عنوان المقالة:تحضير وتشخيص ودراسة تثبيط التأكل لاثنان من ليكيندات قواعد شيف المشتقة من اليوريا والثايو يوريا مع ايونات النحاس والزئبق الثنائي Synthesis, Characterization and the Corrosion Inhibition Study of Two Schiff Base Ligands Derived From Urea and Thiourea and Their Complexes with Cu(II) and Hg(II) Ions
The research includes synthesis of [L1] and [L2] Schiff base ligands by the reaction of vanillin with urea and thiourea respectively in 2:1 mol ratio. The two ligands were reacted with CuII ion in 1:2 mol ratio and HgII ion in 1:1 mol ratio. The prepared compounds have been identified by FTIR, U.V-Vis, 1H-NMR (L1, L2 and HgII complex) spectroscopies, microelemental analysis (C.H.N.S), magnetic susceptibility measurements, atomic absorption, chloride content along with conductivity and melting point measurements. According to applied characterization methods, the proposed general formulas of CuII and HgII complexes were [Cu2LnCl4] and [HgLnCl]Cl, respectively, (where n= 1, 2). The ability of corrosion inhibition with two ligands and their cupper complexes has been studied in diluted hydrochloric acid media.
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وسن محمد علوان | wassan mohammed alwan | 11816