عنوان المقالة:معقدات الفلزات من قواعد شف غير المتجانسة؛ تحضير وتشخيص طيفي ودراسة بيولوجية Metal Complexes of Heterocyclic Hydrazone Schiff-bases; Preparation, Spectral Characterisation and Biological Study
ا.د. انعام اسماعيل يوسف | Enaam Ismail Yousif | 12842
نوع النشر
مجلة علمية
المؤلفون بالعربي
انعام اسماعيل يوسف,رياض محمود ,حسن احمد حسن ومحمد الجبوري
المؤلفون بالإنجليزي
Mohamad J. Al-Jeboori; Enaam I Yousif; Riyadh M. Ahmed; Aeed S. Al-Fahdawi; Hasan A. Hasan
الملخص العربي
New isatinic hydrazone Schiff-base ligands namely; furan-2-carboxylic acid (2-oxo-1,2-dihydro-indol-3-ylidene)-hydrazide) (L1), thiophene-2-carboxylic acid (2-oxo-1,2-dihydro-indol-3-ylidene)-hydrazide (L2) and 2-(pyridine-2-yl-hydrazono)-1,2-dihydro-indol-3-one) (L3) are reported. The ligands were prepared by the condensation of furan-2-carboxylic acid hydrazide (L1), thiophene-2-carboxylic acid hydrazide (L2), and 2-hydrazino pyridine (L3) with isatine. Monomeric complexes were prepared from the reaction of the corresponding metal chloride with the ligands. The ligands and their nine new complexes of the general formulae [M(Ln)2]Cl2 (where M= Co(II), Zn(II) and Cd(II); n= L1, L2 and L3), were characterised by spectroscopic methods (FTIR, UV-Vis, 1H, 13C NMR), elemental analysis, metal content, magnetic measurement and molar conductance. These studies revealed the formation of six coordinate complexes, in which the geometry about metal atom is a distorted octahedral. Biological activity of the ligands and their metal complexes against gram positive bacterial strain Bacillus (G+) and gram negative bacteria Ecoli (G-) are evaluated. The effects of prepared compounds depend on the type of tested bacteria. It is clear that, the ligands and their metal complexes have a potential effect on the gram positive (G+) and gram negative (G-) strains of the tested bacteria.
الملخص الانجليزي
New isatinic hydrazone Schiff-base ligands namely; furan-2-carboxylic acid (2-oxo-1,2-dihydro-indol-3-ylidene)-hydrazide) (L1), thiophene-2-carboxylic acid (2-oxo-1,2-dihydro-indol-3-ylidene)-hydrazide (L2) and 2-(pyridine-2-yl-hydrazono)-1,2-dihydro-indol-3-one) (L3) are reported. The ligands were prepared by the condensation of furan-2-carboxylic acid hydrazide (L1), thiophene-2-carboxylic acid hydrazide (L2), and 2-hydrazino pyridine (L3) with isatine. Monomeric complexes were prepared from the reaction of the corresponding metal chloride with the ligands. The ligands and their nine new complexes of the general formulae [M(Ln)2]Cl2 (where M= Co(II), Zn(II) and Cd(II); n= L1, L2 and L3), were characterised by spectroscopic methods (FTIR, UV-Vis, 1H, 13C NMR), elemental analysis, metal content, magnetic measurement and molar conductance. These studies revealed the formation of six coordinate complexes, in which the geometry about metal atom is a distorted octahedral. Biological activity of the ligands and their metal complexes against gram positive bacterial strain Bacillus (G+) and gram negative bacteria Ecoli (G-) are evaluated. The effects of prepared compounds depend on the type of tested bacteria. It is clear that, the ligands and their metal complexes have a potential effect on the gram positive (G+) and gram negative (G-) strains of the tested bacteria.
تاريخ النشر
22/03/2017
الناشر
Iranian Journal for Science and Technology, Trans. A
رقم المجلد
2017
رقم العدد
41
رابط DOI
DOI 10.1007/s40995-017-0187-z
رابط الملف
تحميل (770 مرات التحميل)
الكلمات المفتاحية
Isatinic hydrazone Schiff-bases  Heterocyclic
رجوع