عنوان المقالة: Synthesis of Highly Porous Mn2O3-Doped Fe3O4 NPs with a Dual Catalytic Function Using Asymmetric Water Soluble Mn-Salen Complex as a Reducing Agent and Template: Catalytic Activity over One-Pot Strecker Synthesis from Alcohols in Recyclable TAIm[CN] Ionic Liquid
Eman Khalaf, Ameer A Alameri, Jitendra Malviya, T Kumar, Farag Altalbawy, Raed HC Alfilh, Milad Kazemnejadi
الملخص الانجليزي
An asymmetric Mn/TEMPO-Salen complex was utilized as a reducing agent and template for the synthesis of Mn/TEMPO-doped Fe3O4 NPs in situ. The subsequent thermal decomposition of Mn/TEMPO-doped Fe3O4 NPs, as a precursor, provides the highly porous (641 m2 g–1) Mn2O3-doped Fe3O4 NPs. The highly porous NPs was characterized by FTIR, BET, TGA, VSM, ICP, TEM, XRD, UV–Vis, and XPS analyses. High stability and catalytic activity was found for the NPs in the synthesis of α-aminonitriles via the Strecker synthesis from primary and secondary alcohols under mild conditions. TAIm[CN] ionic liquid (IL) was used as an efficient solvent and nitrile-required reagent to synthesis of α-aminonitriles. TAIm[CN] IL could be recycled for several times by a simple recovery and subsequent treatment. Also, the catalytic activity of the NPs was evaluated toward the selective alcohol oxidation to carbonyl …
م.م أمير عذاب عبد الكاظم | Ameer Athab Abulkahim AlAmeri | 2868