عنوان المقالة:Electrochemical synthesis of ammonia from wet nitrogen via a dual-chamber reactor using La0.6Sr0.4Co0.2Fe0.8O3−δ-Ce0.8Gd0.18Ca0.02O2−δ composite cathode Electrochemical synthesis of ammonia from wet nitrogen via a dual-chamber reactor using La0.6Sr0.4Co0.2Fe0.8O3−δ-Ce0.8Gd0.18Ca0.02O2−δ composite cathode
إبراهيم علي أحمد عمار | Ibrahim Ali Ahmed Amar | 12538
نوع النشر
مجلة علمية
المؤلفون بالعربي
Ibrahim A. Amar,Rong Lan,John Humphreys,Shanwen Tao
المؤلفون بالإنجليزي
Ibrahim A. Amar,Rong Lan,John Humphreys,Shanwen Tao
الملخص الانجليزي
A La0.6Sr0.4Co0.2Fe0.8O3−δ-Ce0.8Gd0.18Ca0.02O2−δ composite cathode was used to investigate the electrochemical synthesis of ammonia from wet nitrogen. Wet nitrogen was flown through a dual chamber reactor under atmospheric pressure leading to the successful synthesis of ammonia. Ammonia was synthesised at a rate of 1.5 × 10−10 mol s−1 cm−2 at 400 °C when applying a dc voltage of 1.4 V, which is the highest reported to date. This rate is twice that of the observed ammonia formation rate (7 × 10−11 mol s−1 cm−2) when Co-free cathode, La0.6Sr0.4FeO3−δ-Ce0.8Gd0.18Ca0.02O2−δ was used as the cathode catalyst. A higher catalytic activity for ammonia synthesis may be obtained when using a catalyst with high oxygen vacancies, with the introduction of oxygen vacancies at the cathode being a good strategy to improve the catalytic activity of ammonia synthesis.
تاريخ النشر
15/05/2017
الناشر
Catalysis Today
رقم المجلد
286
رقم العدد
رابط DOI
https://doi.org/10.1016/j.cattod.2016.09.006
الصفحات
51-56
رابط الملف
تحميل (416 مرات التحميل)
الكلمات المفتاحية
Electrochemical synthesis Ammonia Oxygen vacancy Oxide-carbonate composite electrolyte La0.6Sr0.4Co0.2Fe0.8O3−δ
رجوع