عنوان المقالة: Complex formation of Cr3+, Mn2 ions using (E)-1-(((3- aminophenyl)imino)methyl)naphthalene-2-ol
أ.د. عبدالسلام معتوق هميل | Prof. Dr. Abdusalam Matoog Hamil | 6221
Publication Type
Journal
Arabic Authors
فرج المهدي اهويدي, خليفة مصباح خليفة وعبدالسلام معتوق هميل
English Authors
*F.S. Almahde , K. M. Khalifa , A.M. Hamil
Abstract
Abstract Metal complexes of Cr(III), Mn(II) of the Schiff base derived from (E)-1-((3- aminophenyl)imino)methyl)naphthalene-2-ol have been prepared and characterized on the basis of physical characteristics, micro-analytical data(CHN), molar conductivity, magnetic moment measurements, Mass spectra, 1HNMR, IR and UV-Vis spectrum data. The elemental analysis data showed the isolated complexes are in 1:1 [M:L] ratio .The obtained molar conductance values revealed the complexes are nonelectrolyte in nature. The results of magnetic moment measurements showed that, the complexes of Cr(III), Mn(II), have unpaired electrons. The infrared spectral data displayed the main coordination sites of (E)-1-((3- aminophenyl)imino) methyl)naphthalene-2-ol towards Cr(III), Mn(II) ions. The electronic spectral results of the Schiff base ligand and its complexes suggest that, the Cr(III), Mn(II) complexes have octahedral and tetrahedral structure.
Publication Date
5/1/2019
Publisher
مجلة العلوم البحثة والتطبيقية Journal of Pure & Applied Sciences
Volume No
18
Issue No
3
ISSN/ISBN
ISSN 2521-9200
Pages
32-36
File Link
تحميل (53 مرات التحميل)
Keywords
Keywords: Schiff base, Complexes, (E)-1-(((3-aminophenyl)imino)methyl)naphthalene-2-ol , 2-hydroxy-1- napthylaldehde ,m-phenylenediamine.
رجوع