Synthesis and characterization of immobilized-polysiloxane monoamine-thiol triacetic acid and its diamine and triamine derivatives -أريد

Publication Type: Journal
Arabic Authors: Mona A Ahmed, Asmah A Abu Shaweesh, Nizam M El-Ashgar, Issa M El-Nahhal, Mohamed M Chehimi, Florence Babonneau
Abstract: In this work, a new porous solid polysiloxane material with thiol-amine-based multiple functional groups polysiloxane-(monoamine-thiol) triacetate, P-(N-S)-TrEA (where P- represents [Si–O]n polysiloxane network), was synthesized using one-pot reaction of TEOS with 3-iminodiethylacetatepropyltrimethoxysilane and 3-thiolethylacetatepropyltrimethoxysilane in the presence of CTAB as a surfactant. Its ethylenediamine and diethylenetriamine-modified polysiloxane-(monoamine-thiol)-tris(N-2-aminoethylacetamide), P-(N-S)-TrEA-NN, and polysiloxane-(monoamine-thiol)-tris(N-3,6-diazahexylacetamide), P-(N-S)-TrEA-NNN, chelating ligand systems were also obtained. The previously reported simple functionalized polysiloxane (monoamine-thiol) has been modified to obtain thiol-monoamine-based multiple functional groups. A variety of methods and techniques including FTIR, solid-state 13C NMR, XPS and TGA have been used for establishing their structure.
Publication Date: 6/1/2016
Publisher: Journal of Sol-Gel Science and Technology
DOI: DOI https:
External Link: https://link.springer.com/article/10.1007/s10971-016-3980-9