عنوان المقالة:الكميات المولية الزائدة في المزيج الثنائي للديبروبيل أمين مع الكحول الأليفاتية في 298.15 K Excess Molar Quantities of Binary Mixture of Dipropyl amine with Aliphatic Alcohols at 298.15 K
حسام سليم خلف | Husam S. Khalaf | 5157
Publication Type
Journal
Arabic Authors
زينب عباس حسن، ظافر تموين الهتيمي، حسام سليم خلف، احمد محمد عباس
English Authors
ZAINAB A. H. AL-DULAIMY, Dhafir T. A. Al-Heetimi, Husam Saleem Khalaf and Ahmed Mohammed Abbas bbas
Abstract
Refractive indices (nD), viscosities (η) and densities (r) were deliberated for the binary mixtures created by dipropyl amine with 1-octanol, 1-heptanol, 1-hexanol, 1-pentanol and tert-pentyl alcohol at temperature 298.15 K over the perfect installation extent. The function of Redlich-Kister were used to calculate and renovated of the refractive index deviations (ΔnD), viscosity deviations (ηE), excess molar Gibbs free energy (ΔG*E) and excess molar volumes(VmE). The standard errors and coefficients were respected by this function. The values of ΔnD, ηE, VmE and ΔG*E were plotted against mole fraction of dipropyl amine. In all cases the obtained ηE, ΔG*E, VmE and ΔnD values were negative at 298.15K. Effect of carbon atoms number in the chain of alcohol and
Publication Date
7/26/2018
Publisher
ORIENTAL JOURNAL OF CHEMISTRY
Volume No
34
Issue No
4
ISSN/ISBN
0970-020 X
DOI
http://dx.doi.org/10.13005/ojc/3404047
Pages
2074-2082
File Link
تحميل (196 مرات التحميل)
Keywords
Binary system, Aliphatic alcohols, Dipropylamine, Viscosity, Refractive index, Density and Excess properties.
رجوع