عنوان المقالة:دراسة بولاروغرافية في حساب إستقرارية المعقدات الجزيئية لمرافق االنزيم NADH مع بعض المستقبالت االلكترونية في المحاليل المائية دراسة بولاروغرافية في حساب إستقرارية المعقدات الجزيئية لمرافق االنزيم NADH مع بعض المستقبالت االلكترونية في المحاليل المائية
رزاق عبدالزهرة إبراهيم حمود العامري | Razzaq Abd Al-Zahra Ibrahim Alamery | 11321
نوع النشر
مجلة علمية
المؤلفون بالعربي
رزاق عبدالزهرة إبراهيم،د.فلاح شريف عبد سهيل
المؤلفون بالإنجليزي
Razzaq Abd Al-Zahra Ibrahim,, Falah Shareef Abed Suhail
الملخص العربي
Co-enzyme NADH is an electro active material, has two polarographic waves at (+0.244V,+0.464V) by (HDME) including (DPP) in pH = 7.4 and T = 370 C, from the different measurements to optimize the ideal conditions for its Polarographic measurement. The acidity function was studied and found it’s inversely proportional with (E1\2) and directly with (id) . The building standard calibration curve is Shown that diffusion current consider as function to concentration according to Ilkovic equation (id = k C). The study formation of molecular complexes found that (Ub0) has shift E1\2 of NADH to high value by (+0.012V), but the other substances have’s shift to less value by ( -0.012, -0.008, -0.007V) for(ATP,Caff.,Vit.C)respectively, from calculation(kr , kf) and estimation (Keq) was equal to (0.96, 35.3, 3.4, 3.0) as well (G 0 ) values are(+0.1,-9.1,-3.1,-2.8) for(Ub0,ATP,Caff.,vit.C) respectively, found (ATP) complex formation is more stable than the other molecular complexes whereas (Ub0) complex was the less stable.
الملخص الانجليزي
Co-enzyme NADH is an electro active material, has two polarographic waves at (+0.244V,+0.464V) by (HDME) including (DPP) in pH = 7.4 and T = 370 C, from the different measurements to optimize the ideal conditions for its Polarographic measurement. The acidity function was studied and found it’s inversely proportional with (E1\2) and directly with (id) . The building standard calibration curve is Shown that diffusion current consider as function to concentration according to Ilkovic equation (id = k C). The study formation of molecular complexes found that (Ub0) has shift E1\2 of NADH to high value by (+0.012V), but the other substances have’s shift to less value by ( -0.012, -0.008, -0.007V) for(ATP,Caff.,Vit.C)respectively, from calculation(kr , kf) and estimation (Keq) was equal to (0.96, 35.3, 3.4, 3.0) as well (G 0 ) values are(+0.1,-9.1,-3.1,-2.8) for(Ub0,ATP,Caff.,vit.C) respectively, found (ATP) complex formation is more stable than the other molecular complexes whereas (Ub0) complex was the less stable
تاريخ النشر
10/04/2016
الناشر
Journal kufa of chemistry
رقم المجلد
4
رقم العدد
10
الصفحات
22-33
رابط الملف
تحميل (235 مرات التحميل)
الكلمات المفتاحية
Polarography, NADH
رجوع